Electron transfer reactions are called oxidation reduction reactions or reactions involving transfer of negative charge (ie. electrons) from one reactant to another. Oxidation and reduction are complementary processes. See the figure for better understanding.
In the above reaction, Sodium (Na) metal is the reducing agent as it supplies electrons for the reduction of chlorine and chlorine is the oxidizing agent as its accepts electrons form sodium thereby sodium gets oxidized.
 
Oxidation vs Reduction
Oxidation  
(with respect to A) 
 | 
  
Reduction  
(with respect to A) 
 | 
 
Oxidation is the loss of
  electrons or hydrogen atoms or gain of oxygen atoms. 
 | 
  
Reduction is the gain of
  electrons or hydrogen atoms or loss of oxygen atoms. 
 | 
 
Removal or loss of electrons 
A ->A++e- 
 | 
  
Addition or gain of
  electrons 
A +e- -> A- 
 | 
 
Removal of Hydrogen 
AH+B -> A+BH 
 | 
  
Addition of Hydrogen 
A+BH ->AH+B 
 | 
 
Addition of oxygen 
A+BO -> AO+B 
 | 
  
Removal of oxygen 
AO+B -> A+BO 
 | 
 
All the above reactions
  releases energy 
 | 
  
All the above reactions
  stores energy 
 | 
 
Examples of oxidation reduction reactions are corrosion,
respiration, the operation of battery etc.

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